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Vanadium(III) sulfate : ウィキペディア英語版
Vanadium(III) sulfate

Vanadium(III) sulfate is the inorganic compound with the formula V2(SO4)3. It is a pale yellow solid that is stable to air, in contrast to most vanadium(III) compounds. It slowly dissolves in water to give the green aquo complex ()3+.
The compound is prepared by treating V2O5 in sulfuric acid with elemental sulfur:〔Robert T. Claunch, Mark M. Jones "Vanadium(III) Sulfate" Inorganic Syntheses, 1963, Volume 7, pages 92–94. 〕
:V2O5 + S + 3 H2SO4 → V2(SO4)3 + SO2 + 3 H2O
This transformation is a rare example of a reduction by elemental sulfur.
When heated in vacuum at or slightly below 410 °C, it decomposes into vanadyl sulfate (VOSO4) and SO2. Vanadium(III) sulfate is stable in dry air but upon exposure to moist air for several weeks forms a green hydrate form.
Vanadium(III) sulfate is a reducing agent.
==References==



抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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